Xi'An, China
CIPAC Meeting 2027
CIPAC Meeting 2027

MT 173 - Colorimetric method for determination of the stability of dilute emulsions


Content Handbook F

 

Outline of method

A dye is dissolved in the emulsifiable concentrate formulation (EC). A sample of the dyed EC is added to a standard water to obtain an aqueous emulsion. At the end of a specified time an aliquot is withdrawn from the emulsion, and transferred to a flask to which propan-2-ol is added to clarify the emulsion. Then the absorbance of the dyed solution is measured in a spectrophotometer and compared to the
absorbance of a similar aliquot taken under the same conditions but at t0 (initial emulsion).

 

Scope

The method is suitable for determining the emulsion stability of dilute emulsions at dilution rates from 0.1 to 2.0%. Alternative conditions concerning standing times, volume of initial emulsion, may be fixed according to a given particular specification.


Failed to start the session because headers have already been sent by "D:\www\www83\plugins\system\debug\src\Extension\Debug.php" at line 377. (500 Whoops, looks like something went wrong.)

RuntimeException RuntimeException

HTTP 500 Whoops, looks like something went wrong.

Failed to start the session because headers have already been sent by "D:\www\www83\plugins\system\debug\src\Extension\Debug.php" at line 377.

Exceptions 2

RuntimeException

in D:\www\www83\libraries\vendor\joomla\session\src\Storage\NativeStorage.php (line 454)
  1. if ($this->isActive()) {
  2. throw new \RuntimeException('Failed to start the session: already started by PHP.');
  3. }
  5. if (ini_get('session.use_cookies') && headers_sent($file, $line)) {
  6. throw new \RuntimeException(
  7. sprintf('Failed to start the session because headers have already been sent by "%s" at line %d.', $file, $line)
  8. );
  9. }
  11. if (!session_start()) {
NativeStorage->start() in D:\www\www83\libraries\src\Session\Storage\JoomlaStorage.php (line 313)
  1. $this->setId($session_clean);
  2. $cookie->set($session_name, '', ['expires' => time() - 3600 ]);
  3. }
  4. }
  6. parent::start();
  8. // Try loading data from the session
  9. if (!empty($_SESSION['joomla'])) {
  10. $this->data = unserialize(base64_decode($_SESSION['joomla']));
  11. }
JoomlaStorage->start() in D:\www\www83\libraries\vendor\joomla\session\src\Session.php (line 396)
  1. {
  2. if ($this->isStarted()) {
  3. return;
  4. }
  6. $this->store->start();
  8. $this->setState(SessionState::ACTIVE);
  10. // Initialise the session
  11. $this->setCounter();
Session->start() in D:\www\www83\libraries\vendor\joomla\session\src\Session.php (line 327)
  1. * @since 1.0
  2. */
  3. public function has($name)
  4. {
  5. if (!$this->isActive()) {
  6. $this->start();
  7. }
  9. return $this->store->has($name);
  10. }
Session->has() in D:\www\www83\libraries\src\Session\Session.php (line 194)
  2. $name = $args[2] . '.' . $name;
  3. }
  4. }
  6. if (parent::has($name)) {
  7. // Parent is used because of b/c, can be changed in Joomla 6
  8. return parent::get($name, $default);
  9. }
  11. /*
Session->get() in D:\www\www83\libraries\src\Factory.php (line 372)
  1. __CLASS__
  2. ),
  3. E_USER_DEPRECATED
  4. );
  6. $instance = self::getApplication()->getSession()->get('user');
  8. if (\is_null($id)) {
  9. if (!($instance instanceof User)) {
  10. $instance = User::getInstance();
  11. }
Factory::getUser() in D:\www\www83\libraries\src\Document\Renderer\Html\ModulesRenderer.php (line 46)
  1. {
  2. $renderer = $this->_doc->loadRenderer('module');
  3. $buffer = '';
  5. $app = Factory::getApplication();
  6. $user = Factory::getUser();
  7. $frontediting = ($app->isClient('site') && $app->get('frontediting', 1) && !$user->guest);
  8. $menusEditing = ($app->get('frontediting', 1) == 2) && $user->authorise('core.edit', 'com_menus');
  10. foreach (ModuleHelper::getModules($position) as $mod) {
  11. $moduleHtml = $renderer->render($mod, $params, $content);
ModulesRenderer->render() in D:\www\www83\libraries\src\Document\HtmlDocument.php (line 578)
  2. $cbuffer[$hash] = $tmpdata;
  4. $cache->store($cbuffer, 'cbuffer_' . $type);
  5. } else {
  6. $this->setBuffer($renderer->render($name, $attribs, null), $type, $name, $title);
  7. }
  9. return parent::$_buffer[$type][$name][$title];
  10. }
HtmlDocument->getBuffer() in D:\www\www83\libraries\src\Document\HtmlDocument.php (line 897)
  1. $replace = [];
  2. $with = [];
  4. foreach ($this->_template_tags as $jdoc => $args) {
  5. $replace[] = $jdoc;
  6. $with[] = $this->getBuffer($args['type'], $args['name'], $args['attribs']);
  7. }
  9. return str_replace($replace, $with, $this->_template);
  10. }
  11. }
HtmlDocument->_renderTemplate() in D:\www\www83\libraries\src\Document\HtmlDocument.php (line 650)
  2. if (\array_key_exists('csp_nonce', $params) && $params['csp_nonce'] !== null) {
  3. $this->cspNonce = $params['csp_nonce'];
  4. }
  6. $data = $this->_renderTemplate();
  7. parent::render($caching, $params);
  9. return $data;
  10. }
HtmlDocument->render() in D:\www\www83\libraries\src\Document\ErrorDocument.php (line 139)
  1. $this->debug = $params['debug'] ?? false;
  2. $this->error = $this->_error;
  4. $params['file'] = 'error.php';
  6. return parent::render($cache, $params);
  7. }
  9. /**
  10. * Render the backtrace
  11. *
ErrorDocument->render() in D:\www\www83\libraries\src\Error\Renderer\HtmlRenderer.php (line 70)
  1. ob_end_clean();
  2. }
  4. $this->getDocument()->setTitle(Text::_('Error') . ': ' . $error->getCode());
  6. return $this->getDocument()->render(
  7. false,
  8. [
  9. 'template' => $template->template,
  10. 'directory' => JPATH_THEMES,
  11. 'debug' => JDEBUG,
HtmlRenderer->render() in D:\www\www83\libraries\src\Exception\ExceptionHandler.php (line 142)
  1. 'subject' => $app,
  2. 'document' => $renderer->getDocument(),
  3. ])
  4. );
  6. $data = $renderer->render($error);
  8. // If nothing was rendered, just use the message from the Exception
  9. if (empty($data)) {
  10. $data = $error->getMessage();
  11. }
ExceptionHandler::render() in D:\www\www83\libraries\src\Exception\ExceptionHandler.php (line 76)
  1. * @since 3.10.0
  2. */
  3. public static function handleException(\Throwable $error)
  4. {
  5. static::logException($error);
  6. static::render($error);
  7. }
  9. /**
  10. * Render the error page based on an exception.
  11. *
ExceptionHandler::handleException() in D:\www\www83\libraries\src\Application\CMSApplication.php (line 334)
  1. );
  3. // Trigger the onError event.
  4. $this->dispatchEvent('onError', $event);
  6. ExceptionHandler::handleException($event->getError());
  7. }
  9. // Trigger the onBeforeRespond event.
  10. $this->dispatchEvent(
  11. 'onBeforeRespond',
CMSApplication->execute() in D:\www\www83\index.php (line 35)
  2. // Run the application - All executable code should be triggered through this file
  3. require_once dirname(__FILE__) . '/includes/app.php';
  5. $app = JFactory::getApplication('site');
  6. $app->execute();

RuntimeException

Failed to start the session because headers have already been sent by "D:\www\www83\plugins\system\debug\src\Extension\Debug.php" at line 377.

in D:\www\www83\libraries\vendor\joomla\session\src\Storage\NativeStorage.php (line 454)
  1. if ($this->isActive()) {
  2. throw new \RuntimeException('Failed to start the session: already started by PHP.');
  3. }
  5. if (ini_get('session.use_cookies') && headers_sent($file, $line)) {
  6. throw new \RuntimeException(
  7. sprintf('Failed to start the session because headers have already been sent by "%s" at line %d.', $file, $line)
  8. );
  9. }
  11. if (!session_start()) {
NativeStorage->start() in D:\www\www83\libraries\src\Session\Storage\JoomlaStorage.php (line 313)
  1. $this->setId($session_clean);
  2. $cookie->set($session_name, '', ['expires' => time() - 3600 ]);
  3. }
  4. }
  6. parent::start();
  8. // Try loading data from the session
  9. if (!empty($_SESSION['joomla'])) {
  10. $this->data = unserialize(base64_decode($_SESSION['joomla']));
  11. }
JoomlaStorage->start() in D:\www\www83\libraries\vendor\joomla\session\src\Session.php (line 396)
  1. {
  2. if ($this->isStarted()) {
  3. return;
  4. }
  6. $this->store->start();
  8. $this->setState(SessionState::ACTIVE);
  10. // Initialise the session
  11. $this->setCounter();
Session->start() in D:\www\www83\libraries\vendor\joomla\session\src\Session.php (line 327)
  1. * @since 1.0
  2. */
  3. public function has($name)
  4. {
  5. if (!$this->isActive()) {
  6. $this->start();
  7. }
  9. return $this->store->has($name);
  10. }
Session->has() in D:\www\www83\libraries\src\Session\Session.php (line 194)
  2. $name = $args[2] . '.' . $name;
  3. }
  4. }
  6. if (parent::has($name)) {
  7. // Parent is used because of b/c, can be changed in Joomla 6
  8. return parent::get($name, $default);
  9. }
  11. /*
Session->get() in D:\www\www83\libraries\src\Factory.php (line 372)
  1. __CLASS__
  2. ),
  3. E_USER_DEPRECATED
  4. );
  6. $instance = self::getApplication()->getSession()->get('user');
  8. if (\is_null($id)) {
  9. if (!($instance instanceof User)) {
  10. $instance = User::getInstance();
  11. }
Factory::getUser() in D:\www\www83\libraries\src\Application\SiteApplication.php (line 565)
  1. *
  2. * @since 3.2
  3. */
  4. protected function initialiseApp($options = [])
  5. {
  6. $user = Factory::getUser();
  8. // If the user is a guest we populate it with the guest user group.
  9. if ($user->guest) {
  10. $guestUsergroup = ComponentHelper::getParams('com_users')->get('guest_usergroup', 1);
  11. $user->groups = [$guestUsergroup];
SiteApplication->initialiseApp() in D:\www\www83\libraries\src\Application\SiteApplication.php (line 237)
  1. * @since 3.2
  2. */
  3. protected function doExecute()
  4. {
  5. // Initialise the application
  6. $this->initialiseApp();
  8. // Mark afterInitialise in the profiler.
  9. JDEBUG ? $this->profiler->mark('afterInitialise') : null;
  11. // Route the application
SiteApplication->doExecute() in D:\www\www83\libraries\src\Application\CMSApplication.php (line 304)
  1. $this->sanityCheckSystemVariables();
  2. $this->setupLogging();
  3. $this->createExtensionNamespaceMap();
  5. // Perform application routines.
  6. $this->doExecute();
  8. // If we have an application document object, render it.
  9. if ($this->document instanceof \Joomla\CMS\Document\Document) {
  10. // Render the application output.
  11. $this->render();
CMSApplication->execute() in D:\www\www83\index.php (line 35)
  2. // Run the application - All executable code should be triggered through this file
  3. require_once dirname(__FILE__) . '/includes/app.php';
  5. $app = JFactory::getApplication('site');
  6. $app->execute();

Stack Traces 2

[2/2] RuntimeException 
RuntimeException:
Failed to start the session because headers have already been sent by "D:\www\www83\plugins\system\debug\src\Extension\Debug.php" at line 377.

  at D:\www\www83\libraries\vendor\joomla\session\src\Storage\NativeStorage.php:454
  at Joomla\Session\Storage\NativeStorage->start()
     (D:\www\www83\libraries\src\Session\Storage\JoomlaStorage.php:313)
  at Joomla\CMS\Session\Storage\JoomlaStorage->start()
     (D:\www\www83\libraries\vendor\joomla\session\src\Session.php:396)
  at Joomla\Session\Session->start()
     (D:\www\www83\libraries\vendor\joomla\session\src\Session.php:327)
  at Joomla\Session\Session->has()
     (D:\www\www83\libraries\src\Session\Session.php:194)
  at Joomla\CMS\Session\Session->get()
     (D:\www\www83\libraries\src\Factory.php:372)
  at Joomla\CMS\Factory::getUser()
     (D:\www\www83\libraries\src\Document\Renderer\Html\ModulesRenderer.php:46)
  at Joomla\CMS\Document\Renderer\Html\ModulesRenderer->render()
     (D:\www\www83\libraries\src\Document\HtmlDocument.php:578)
  at Joomla\CMS\Document\HtmlDocument->getBuffer()
     (D:\www\www83\libraries\src\Document\HtmlDocument.php:897)
  at Joomla\CMS\Document\HtmlDocument->_renderTemplate()
     (D:\www\www83\libraries\src\Document\HtmlDocument.php:650)
  at Joomla\CMS\Document\HtmlDocument->render()
     (D:\www\www83\libraries\src\Document\ErrorDocument.php:139)
  at Joomla\CMS\Document\ErrorDocument->render()
     (D:\www\www83\libraries\src\Error\Renderer\HtmlRenderer.php:70)
  at Joomla\CMS\Error\Renderer\HtmlRenderer->render()
     (D:\www\www83\libraries\src\Exception\ExceptionHandler.php:142)
  at Joomla\CMS\Exception\ExceptionHandler::render()
     (D:\www\www83\libraries\src\Exception\ExceptionHandler.php:76)
  at Joomla\CMS\Exception\ExceptionHandler::handleException()
     (D:\www\www83\libraries\src\Application\CMSApplication.php:334)
  at Joomla\CMS\Application\CMSApplication->execute()
     (D:\www\www83\index.php:35)
[1/2] RuntimeException 
RuntimeException:
Failed to start the session because headers have already been sent by "D:\www\www83\plugins\system\debug\src\Extension\Debug.php" at line 377.

  at D:\www\www83\libraries\vendor\joomla\session\src\Storage\NativeStorage.php:454
  at Joomla\Session\Storage\NativeStorage->start()
     (D:\www\www83\libraries\src\Session\Storage\JoomlaStorage.php:313)
  at Joomla\CMS\Session\Storage\JoomlaStorage->start()
     (D:\www\www83\libraries\vendor\joomla\session\src\Session.php:396)
  at Joomla\Session\Session->start()
     (D:\www\www83\libraries\vendor\joomla\session\src\Session.php:327)
  at Joomla\Session\Session->has()
     (D:\www\www83\libraries\src\Session\Session.php:194)
  at Joomla\CMS\Session\Session->get()
     (D:\www\www83\libraries\src\Factory.php:372)
  at Joomla\CMS\Factory::getUser()
     (D:\www\www83\libraries\src\Application\SiteApplication.php:565)
  at Joomla\CMS\Application\SiteApplication->initialiseApp()
     (D:\www\www83\libraries\src\Application\SiteApplication.php:237)
  at Joomla\CMS\Application\SiteApplication->doExecute()
     (D:\www\www83\libraries\src\Application\CMSApplication.php:304)
  at Joomla\CMS\Application\CMSApplication->execute()
     (D:\www\www83\index.php:35)