Handbook F

Analysis of technical and formulated pesticides

Freezing point	MT 1
Melting point	MT 2
Specific gravity and density, hydrometer method	MT 3.1
Specific gravity and density, pyknometer method	MT 3.2
Specific gravity and density, suspension concentrates	MT 3.3
Acetone soluble material, solution at room temperature	MT 5.2
Solubility in acetone	MT 5
Acetone soluble material, solution, hot solution	MT 5.1
Solubility in hexane	MT 6
Solubility in ethanol	MT 7
Ethanol soluble material, hot solution	MT 7.1
Ethanol soluble material, solution at room temperature	MT 7.2
Kerosene insoluble material	MT 8
Water soluble material	MT 9
Water insoluble material, hot solution of the sample	MT 10.1
Water insoluble material, cold solution of the sample	MT 10.2
Water insoluble material, coarse material-water insoluble	MT 10.3
Water insoluble material in pesticide aqueous solutions	MT 10.4
Xylene insoluble material	MT 11
Flash point, Abel method	MT 12.1
Flash point, tag closed tester	MT 12.2
Flash point, Pensky-Martens closed tester	MT 12.3
Freezing mixtures (5 ± 1°C)	MT 14.1
Freezing mixtures (10 ± 1°C)	MT 14.2
Suspensibiity of water dispersible powders, CIPAC method	MT 15.1
Suspensibiity of water dispersible powders, AID method	MT 15.2
Dichlorodifluoro-methane, insoluble material	MT 16
Loss on drying, oven drying at 60°C	MT 17.1
Loss on drying, vacuum drying at 45°C, 24 h	MT 17.2
Loss on drying, over drying at 100°C at constant weight	MT 17.3
Loss on drying, vacuum drying at room temperature	MT 17.4
Standard waters, CIPAC standard waters A - G	MT 18.1
Standard waters, H and J	MT 18.2
Standard waters, non-CIPAC standard waters	MT 18.3
Buffer solutions, phosphate buffer	MT 19
Dilute emulsion stability	MT 20
Silica for chromatography, silica	MT 21.1
Silica for chromatography, sorbisil M60	MT 21.2
Silica for chromatography, fiorisil	MT 21.3
Viscosity of transparant and opaque liquids	MT 22.1
Viscosity Redwoood	MT 22.2
Viscosity of mileral oil	MT 22
Miscibility with hydrocarbon oil	MT 23
Phosphorus pentoxide	MT 24
Sand for germination tests	MT 25
John Innes Potting compost for soil testing of seed germination	MT 26
Acetone, insoluble material	MT 27
Dimedone derivative	MT 28
Sulphated ash, general method	MT 29
Water, Karl Fisher method	MT 30
Water, Dean and Stark method	MT 30.2
Water, free water 'speedy' method	MT 30.3
Water, in acetone solutions	MT 30.4
Free acidity or alkalinity, methyl red indicator method	MT 31.1
Free acidity or alkalinity, electrometric procedure	MT 31.2
Free acidity or alkalinity, acidity of petroleum products	MT 31.3
Conductivity, determination of	MT 32
Tap density of powders	MT 33
Dustability test after accelerated storage	MT 34
Oil insoluble material	MT 35
Emulsion characteristics of emulsifiable concentrates, 5% v/v oil phase when diluted	MT 36.1
Emulsion characteristics of emulsifiable concentrates, dispersion stability of aqueous emulsions	MT 36.2
Isolation of active ingredient, extraction with acetone	MT 37.1
Isolation of active ingredient, extraction with light petroleu m	MT 37.2
Organic chlorine, potassium-xylene method	MT 38.1
Organic chlorine, Stepanov method	MT 38.2
Organic chlorine, semi-micro determination of total chlorine	MT 38.3
Low temperature stability, emulsifiable concentrates and solutions	MT 39.1
Low temperature stability, aqueous solutions	MT 39.2
Water content and suspended solids, water content	MT 40.1
Water content and suspended solid, suspended solids	MT 40.2
Dilution stability	MT 41
Particle size, formulations without carriers	MT 42.1
Particle size, formulations containing carriers	MT 42.2
Partile size distribution of a DDT dipersible powder	MT 43
Flowability of powders	MT 44
Removal of dyes	MT 45
Accelerated storage tests by heating, general methods	MT 46.1
Accelerated storage tests by heating, special methods	MT 46.2
Foaming, persistent	MT 47.1
Foaming, persistent of suspension concentrates	MT 47.2
Stability of undiluted tar oil products, miscible type	MT 48.1
Stability of undiluted tar oil products, stock emulsion type	MT 48.2
Stability of diluted tar and petroleum oil products, tar-oils-miscible and stock emulsion types	MT 49.1
Stability of diluted tar and petroleum oil products, petroleum oil-miscible type	MT 49.2
Alumina, Brockmann activity grade III	MT 50
Stability of tar-petroleum and petroleum oil products-undiluted, miscible type	MT 51.1
Stability of diluted and petroleum oil concentrate products, miscible type	MT 52.1
Wettability	MT 53
Evaluation of wettability, wetting time of a standard type	MT 53.1
Evaluation of wettability, wetting of leaf surfaces	MT 53.2
Evaluation of wettability, wetting of dispersible powders	MT 53.3
Stability of undiluted DNOC-petroleum, petroleum and tar-petroleum oil products	MT 54
Stabiliby of siluted oil products, tar-petroleum oil	MT 55.1
Stabiliby of siluted oil products, petroleum and DNOC petroleum oils	MT 55.2
Stabiliby of siluted oil products, petroleum oils for orchard use	MT 55.3
Stabiliby of siluted oil products, petroleum oils for glasshouse use	MT 55.4
Volatility of neutral oil, preliminary examination	MT 56.1
Volatility of neutral oil, full method	MT 56.2
Unsulphonated residue of neutral oil	MT 57
Dust content and apparant density of granular formulations, sampling	MT 58.1
Dust content and apparant density of granular formulations, preperation of the sample	MT 58.2
Dust content and apparant density of granular formulations, apparent density after compactation without pressure Dust content and apparant density of granular formulations, apparent density after compactation without pressure	MT 58.3
Sieve analysis, dry sieving-dusts	MT 59.1
Sieve analysis, dry sieving-granular products	MT 59.2
Sieve analysis, wet sieving	MT 59.3
Sieve analysis, sieve test for granular material	MT 59.4
Rate of solution of the sodium salts of phenoxylkanoic acid herbicides and their solid formulations	MT 60
Neutral oil, determination of distillation range	MT 64
Hydrolysable organic chlorine, HCH and lindane dried residues, or technical materials	MT 64.1
Hydrolysable organic chlorine, HCH or lindane dusts and dispersible powders	MT 64.2
Hydrolysable organic chlorine, DDT residues of technical material	MT 64.3
Hydrolysable organic chlorine, HCH or lindane emulsifiable concentrates and solutions	MT 64.4
Hydrolysable organic chlorine, DDt dusts and dispersible powders	MT 64.5
Hydrolysable organic chlorine, DDT emulsifiable concentrates and solutions	MT 64.6
Organochlorine pesticdes, determination in aqueous emulsions	MT 65
Free acidity of phenoxyalkanoic esters	MT 66
Fat extraction apparatus	MT 67
Chlorides in phenoxyalkanoic acids	MT 68.1
Free phenols in phenoxyalkonoic herbicides, GLC method	MT 69
Solubility in sodium hydroxide, phenoxyalkanoic herbicides	MT 71.1
Solubility in sodium hydroxide, creosols	MT 71.2
Solubility in sodium hydroxide, bromoxynil and ioxynil	MT 71.3
Hardness of water	MT 73
Neutrility	MT 74
pH, determination of	MT 75
pH values, determination of, general method	MT 75.1
pH of aqueous dispersions	MT 75.2
Solubility in triethanolamine	MT 76
1-Chloro-2,3-epoxyethane	MT 77
Epichlorhydrin	MT 77
Hydrogen sulphide and thiols	MT 78
Acid wash test	MT 79
Residue on evaporation, low boiling products	MT 80.1
Residue on evaporation, creosols	MT 80.2
Soluble alkalinity	MT 81
Soluble chlorides	MT 82
Seed adhesion test for powders for seed treatment	MT 83
Ignition tests, assessment of spontaneous ignition potential of dithiocarbamates	MT 84.1
Kieselguhr, for GLC	MT 86.1
Kieselguhr, for GLC, for partition chromatography	MT 86.2
Chloroform solubles, hot solutions	MT 87.1
Chloroform solubles, cold solutions	MT 87.2
Toluene solubles	MT 90
Lead, dithizone general	MT 92.1
Lead, dithizone method B	MT 92.2
Manganese, bismuthate method	MT 93.1
Manganese, EDTA method	MT 93.2
Zinc in dithiocarbamates	MT 94.1
Iron, determination of	MT 95
Separation and identification of herbicides	MT 97
Copper, water soluble, colorimetric method with bathocuproine	MT 98.1
Copper, water soluble, atomic absorption method	MT 98.2
Determination of arsenic	MT 99
Total chlorides	MT 100
Heptane-insoluble material	MT 101
Nitron, preperation of complexes	MT 105
Ammonia-ammonium chloride buffer solution pH 10	MT 107
Dinitro compounds, solubility of salts and alkali insolubles	MT 108
Moneral acidity of dinitro compounds	MT 109
Mercury, mercurial impurities in technical and formulated mercury compounds	MT 110
Silanization of gas chromatographic columns	MT 113
Correction of interfering peaks	MT 114
Mercury (II) salts, characteristic reactions of	MT 116
Chlorides, test for	MT 117
Iodides, test for	MT 118
Phosphates, test for	MT 120
Silicates, test for	MT 121
Extractable acids, determination of	MT 126
Extractable acids, melting point of	MT 127
Gaschromatography of phenoxyalkanoic acids and other herbicides	MT 129
Dithiocarbamates, identity test for certain alkylenebis	MT 130
Dithiocarbamates, identity test for certain dithiocarbamates and thiram and their mixtures	MT 130
Nitrophenols, determination of	MT 133
2-Aminopyridine, preparation of complexes of nitro compounds	MT 134
Urea herbicides, identification of	MT 137
Pour point of mineral oil	MT 139
Free amines in urea herbicides	MT 141
Detection and identification of impurities in substituted phenylurea herbicides	MT 142
Phosphorus in active ingredients, spectrophotometric determination after TLC separation	MT 145
Oil content of emulsifiable concentrates	MT 146
Retention test of seed treatment powders	MT 147
Pourability of suspension concentrates	MT 148
Packing of columns for gaschromatography	MT 149
TCDD, determination in 2,4,5-T technical esters	MT 151.1
Identification of amines	MT 152
Dithiocarbamates, qualitative procedure for confirmation of the presence of a dithiocarbamate or thiuram disulphide	MT 153
Thiram, qualitative procedure for confirmation of the presence of	MT 153
Dithiocarbamates, determination of anions	MT 154
Free phenols in phenoxyalkanoic herbicides, HPLC method	MT 155
Water solubility, prelimenary test	MT 157.1
Water solubility, column elution method	MT 157.2
Water solubility, flask method	MT 157.3
Mercury, determination on treated seed	MT 158
Pour and tap bulk density of granular materials	MT 159
Spontaneity of dispersion, suspension concentrates	MT 160
Suspensibility of aqueous suspension concentrates	MT 161
ETU, determinaton in ethylenebisdithiocarbamates	MT 162
Cypermethrin, identity test	MT 163
Fenvalerate, identity test	MT 163
Identity tests for permethrin, cypernethrin and fenvalerate	MT 163
Permethrin, identity test	MT 163
Bupirimate, identity test	MT 164
Ethirimol, identity test	MT 164
Identity tests fir pirimicarb, buprimate, ethirimol, pirimiphos-ethyl and pirimiphos-methyl	MT 164
Pirimicarb, identity test	MT 164
Pirimiphos-ehtyl, identity test	MT 164
Pirimicarb-methyl, identity test	MT 164
Ultraviolet absorption test for ethylenebisdithiocarbamates	MT 165
Sampling of water dispersible granules	MT 166
Sieve analysis, wet sieving water dispersible granules	MT 167
Suspensibility of water dispersible granules	MT 168
Tap density of water dispersible granules	MT 169
Sieve analysis, dry sieving of water dispersible granules	MT 170
Dustiness of granular products	MT 171
Flowability of water dispersible granules	MT 172
Dilute emulsion stability, colorimetric method	MT 173
Emulsion characteristics of emulsifiable concentrates of the stability of emulsions	MT 173
Spontaneity of dispersion of water dispersible granules	MT 174
Determination of seed-to-seed uniformuity of distribution for liquid seed treatment formulations	MT 175
Dissolution rate of water soluble bags	MT 176
Suspensibility of water dispersible powders, simplified CIPAC method	MT 177